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dc.contributor.authorJohnson, Patricia N.
dc.date.accessioned2021-09-07T19:23:48Z
dc.date.available2021-09-07T19:23:48Z
dc.date.issued2015-04-10
dc.identifier.urihttp://hdl.handle.net/1951/72675
dc.description.abstractPolynuclear molecular designs are attractive for light absorption over a broad spectral range, particularly when multiple chromophores may be incorporated into a single scaffold. The ability of Re(I) to accommodate a variety of ligands while maintaining efficient absorption and emission properties motivates its use in metallacycles and cages intended for light harvesting applications. Towards this end, a multidentate N-donor ligand with imine sites was selected for the formation of dinuclear complexes. The ligand is formed from ethylenediamine, 1,4-benzenedicarboxaldehyde, and 2,4,6-trimethylbenzaldehyde through a series of Schiff-base condensation reactions. Metalation is envisioned by treatment with Re(CO)_5Br, resulting in the loss of two carbonyl ligands. Photophysical investigations will establish the extent of electronic communication between the metal centers and evaluate the emissive properties of the dinuclear complex.
dc.language.isoen_US
dc.subjectChromophore
dc.subjectRhenium
dc.subjectSupramolecule
dc.subjectPolynuclear Complex
dc.subjectMetallacycle
dc.titleSynthesis and Photophysical Investigations of Polynuclear Rhenium(I) Compounds Containing Bridging Imine Donors
dc.typeposter_presentation
dc.contributor.organizationUniversity at Buffalo, State University of New York
dc.description.institutionSUNY Brockport
dc.description.publicationtitleSUNY Undergraduate Research Conference
dc.source.statuspublished


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